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Records relating to the Brigstocke family, including deeds of properties in Carmarthenshire and Pembrokeshire prior their acquisition by the Brigstockes, 1496-1889; deeds and documents of members of the Brigstocke family, 1655-1912; miscellaneous deeds, documents and papers relating to the Brigstocke family and lands in Carmarthenshire, including the Dolhaidd estate, 1846-1892, Cenarth, 1741-1838, and Llandyfaelog and Kidwelly, 1772-1833; legal papers, 1751-1775; and deeds and documents collected by W. Evans George relating to other estates, including: papers of the Lewes family of Gellidywyll, mostly bills and receipts, 1741-1792; draft deeds of W. Evans George for property in the Lower Teifi Valley, Cardiganshire and Carmarthenshire, 1896-1922; sale and account books of W. Evans George and Sons, 1863-1884; printed material, 1837-1925; papers concerned with local elections in Cardiganshire, 1741-1937; weekly account book of the surveyor of the South Wales Highway for Llanfihangel-ar-arth, 1866-1873; records of the Court of Petty Sessions, Penrhiw-pal, Cardiganshire, 1903-1927; and records of the Newcastle Emlyn Town Improvement Committee, 1903-1906.

Accounts of the grocer William Evans, 1913-1945; together with some receipts, 1898-1923, a tithe bill, 1898 and tenancy documents for properties in Llanfihangel Penbedw, Llanfair Nant-gwyn, Castellan Chapel and Penrith (Penrhydd), [Pembrokeshire].

Research papers of Wynford Davies, 1961-1980s, mainly on educational matters, including notes compiled by him in preparing his book, The Curriculum & Organization of the County Intermediate Schools, 1880-1926 (1989); research papers on intermediate education in Wales, 1970s-1980s and correspondence on small rural schools, 1961-1966.

A copy of part of Chetham Library MS 6715 containing Wyth ran rhieni, being pedigrees to great grandparents, together with coats of arms of the noblemen and gentry of Pembrokeshire.

Papers, [1300]-1936, from the library of Mrs Ethel Jones of Aberystwyth comprising material of Pembrokeshire interest, including estate rentals, farm accounts, correspondence relating to land tenure, rules of Milford Friendly Society and turnpike gate receipts at Haverfordwest; papers of or relating to the Goldwyer family of Marlborough and [?Bristol] which include a tour journal of 1799 and correspondence; together with miscellaneous accounts, legal precedents, correspondence and a volume of coats of arms, much of which material also relates to Pembrokeshire.

Miscellaneous legal and other letters and papers, 1765-1843, mainly of Pembrokeshire interest and including letters sent by John Swale of Lincoln's Inn, etc., to Richard Knethell, attorney-at-law, Hook, near Haverfordwest, other recipients of letters being John Bateman, Haverfordwest, W. B. Thomas, vicar of Steynton, and William Evans, solicitor, Haverfordwest.

Miscellaneous manuscript and printed material, 1775-1870, relating to Captain John Phillips of Liverpool, his heirs, and the Smalls Lighthouse on the Pembrokeshire coast, the building of which he instigated, including two broadsides, articles of agreement, legal opinions, autograph letters and the signed document by which Phillips transferred the management of the lighthouse to Trinity House.