Title deeds of the Dinefwr estate, 1514-20 cent., in Carmarthenshire, Glamorgan and Pembrokeshire; rentals and accounts, 1587-1777; court rolls of the manor of Iscennen, 1660-1710; a series of copies of royal grants, 1481-1517, to Sir Rhys ap Thomas; and documents relating to the attainder of Rice Griffith, 1531, and to efforts to reverse the attainder, 1547 to temp. James I; records of the Neath Abbey estate, including records of the manor of Cadoxton-juxta-Neath, from 1602; and coal-mining records, Glamorgan, 18 cent.-19 cent.

Biographical notes on Sir Robert Mansel and the Button family; notes on the bardic order, on Margam and on customs, notions, pastimes and diversions prevalent in Glamorgan; lists of manors, notes on abbeys and priories, and a list of bishops of Llandaff. The work is mainly that of William Davies, Cringell, but with additions by Richard Bevan and Edward Williams ('Iolo Morganwg').

Llangibby Castle estate records, including court rolls of manors in Monmouthshire, 1262-1911, Glamorgan, 1675-1739, Gloucestershire, 1427-1595, and Somerset, 1609-1691; title deeds, mainly Monmouthshire, 1217-1930, and correspondence, mainly 18-19 cent.; important letters and papers relating to the civil war in Monmouthshire; and manuscripts aquired by the family, including drafts and copies of Modus Tenendi Parliamentarum and Observata Parliamentaria by Henry Elsynge, junior (1598-1654), clerk to the House of Commons, together with minutes of the House of Commons, 1624-1626, calendar of the Journal of the House of Lords, 1647-1768, copies of the Journals of the House of Commons, 1547-1701, index to parliamentary proceedings, temp. Edward III-Edward IV, and, 1724-1743, civil war tracts, the journal of the missionary Dr Joseph Wolff, 1832, 'Prif Achae holh Gymru Benbaladr' in the autograph of Sir Thomas Wiliams, Trefriw, 1578-1609, a seventeenth-century collection of Welsh poetry by the principal 'cywyddwyr'; a memoir of Richard Robert Jones ('Dic Aberdaron', 1780-1843) in his own autograph; English sermons and miscellaneous notes by Rev. Edmund Jones, Pontypool, a sermon notebook of Rev. Philip Henry (1631-1696), the eminent Nonconformist divine, a survey of the lands of Henry, earl of Pembroke, in Glamorgan and Monmouthshire, 1570, and a survey of lands in the lordship of Usk, 1619; pedigree rolls of Sir Roger Williams of Penrhos, Monmouthshire, compiled by Thomas Jones ('Twm Siôn Catti'), 1591, and of the Williams family of Llangibby Castle, probably compiled by Sylvanus Morgan.

Ministers' accounts for the year ending at Michaelmas 1598 of the manors, lands and possessions in Glamorgan of Henry Herbert, second Earl of Pembroke, Lord Herbert of Cardiff, lord Par of Ros and Kendal, lord Marmion and St Quentin, lord President of Wales, and Knight of the Garter.